Tetrakis(4-methoxyanilinium) hexachloridobismuthate(III) chloride monohydrate
نویسنده
چکیده
In the crystal of the title compound, (C(7)H(10)NO)(4)[BiCl(6)]Cl·H(2)O, the Bi(III) cation is located on an inversion center and coordinated by six Cl(-) anions in a slightly distorted octa-hedral geometry; the uncoordinated Cl(-) anion and lattice water mol-ecule are located on a twofold rotation axis. Two independent 4-meth-oxy-anilinium cations are linked to the Bi complex, the uncoordinated Cl(-) anion and lattice water mol-ecule via N-H⋯Cl and N-H⋯O hydrogen bonds.
منابع مشابه
Tetrakis(2-amino-6-methylpyridinium) hexachloridobismuthate(III) chloride monohydrate
The asymmetric unit of the title compound, (C(6)H(9)N(2))(4)[BiCl(6)]Cl·H(2)O, contains four protonated 2-amino-6-methyl-pyridine (HAMP) cations and two-halves of two [BiCl(6)](3-) anions, together with one water mol-ecule and one chloride anion. The Bi(III) atoms are hexa-coordinated by Cl atoms, forming distorted octa-hedral geometries. In the crystal structure, intra-molecular O-H⋯Cl and N-H...
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